White lithium grease is a semi-solid lubricant made from three things: a base oil that does the actual lubricating, a lithium soap thickener that holds that oil in place, and additives that give the product its white color and its staying power. The white comes from a pigment such as zinc oxide; some formulas also carry PTFE (polytetrafluoroethylene) for extra slip under load.
Think of a grease lubricant as oil plus a sponge. The lithium soap is the sponge. Squeeze a bearing or a hinge and the sponge releases oil at the contact points; release the pressure and it soaks the oil back up. That's why grease stays on a vertical surface for a season while penetrating oil is gone by the weekend.
Lithium soap dominates the market because it handles water and moderate heat better than the cheaper soda- and calcium-based thickeners it replaced, and it works with a wide range of base oils.
White Lithium Grease vs. Lithium Complex Grease vs. White Lithium Grease Spray
This is the question that sends people to Reddit before they reach the checkout, so here's the short answer.
"White lithium grease" and "white lithium grease spray" are the same product in a different can. If the label says white lithium and the can is an aerosol, you're holding an aerosol version of the same lithium-soap grease sold in tubes. The spray version is thinned with a carrier so it can atomize; the carrier flashes off in a minute or two and leaves the grease behind. Buy either one with confidence.
Regular lithium grease is usually the same thickener family without the white pigment, so it's often amber, brown or red, frequently loaded with extra-pressure additives for chassis and wheel bearings. It lubricates just as well. You simply can't see where it went, which matters more than it sounds when you're checking your work on a door track.
Lithium complex grease is the upgrade. The thickener is built with a second acid, which pushes the dropping point higher and lets it withstand more heat and heavier loads. If a part runs hot or carries real weight, lithium complex is the better call. For hinges, tracks, cables and household hardware, standard white lithium is plenty.
Grease Lubricant Basics: PTFE, Lithium Soap & Lubrication Film
Three numbers on a label tell you most of what you need. Base oil viscosity sets how easily the film flows into a tight joint. NLGI grade describes how stiff the grease is (more on that below). PTFE content, when present, adds a dry-film component that keeps surfaces apart during the moment of startup, before the oil film builds.
That layer is the whole point. Metal on metal without a lubrication film means galling, squeal and wear. A few thousandths of grease reduces that contact to almost nothing, and because it doesn't drain away, it's still there next month.